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· Phosphogypsum is the by-product of phosphate of fertilizer or phosphate which causes serious environmental pollution. In this work, a series of phosphogypsum whiskers were prepared using phosphogypsum as raw materials and NH 4 Cl as additive through the atmospheric water solution method. The results showed that the ammonium chloride solution has a great influence on …
More DetailsAmmonium sulfate is well known for the first order phase transition which occurs upon cooling to a Ferro-electric crystal. Ammonium sulfate is made by treating ammonia, often as a by-product from coke-ovens, with sulfuric acid-2 . Ammonium sulfate also is manufactured from gypsum (CaSO4·2H2O).
More Details· applications. It targets the possibility of utilizing gypsum board waste to produce new gypsum boards or to produce non-load bearing gypsum bricks. To meet this objective, flexural strength test was conducted for the gypsum boards samples. Moreover, standard tests such as
More Details· For example, ammonium sulfate [(NH 4) 2 SO 4] fertilizer mixed with water forms ammonium (NH 4 +) and sulfate (SO 4-2). In soils, bacteria convert ammonium into nitrate through a process called nitrification. Plants may use nitrogen in either the ammonium or the nitrate form, but most nitrogen is taken up as nitrate.
More DetailsThe hypersaline sediment and groundwater of playa lake, Lake Lucero, at the White Sands National Monument in New Mexico were examined for microbial community composition, geochemical gradients, and mineralogy during the dry season along a meter and a half depth profile of the sediment vs. the groundwater interface. Lake Lucero is a highly dynamic environment, strongly characterized by the ...
More DetailsAbstract: More economical and effective technology is being developedin the wastewater treatment process to deal with the products of phenylhydrazine hydrochloride (PHH). Fixed ammonium in the effluent is converted to free ammonia by utilizing the neutralization reaction, and the sulfate is removed in the form of gypsum.
More Details· Amjad, Z., " Calcium sulfate dihydrate (gypsum) ... Christov, C., " Thermodynamic study of quaternary systems with participation of ammonium and sodium alums and chromium alums," Calphad 26, 341 ... (Columbia University, New York, 2012). Google Scholar; 39.
More DetailsThe invention discloses a chemical gypsum-to-ammonium sulfate reaction slurry concentration, waste heat recovery and waste ammonia recovery method. The method comprises a step of pretreatment, a step of ammonia water dissolution, a step of carbonation fixation reacting, a step of concentration and recovery, and a step of filtration, drying and evaporating crystallization.
More Details· One of the ways of utilizing FGD gypsum is a conversion reaction with CO 2 and ammonia with the formation of ammonium sulfate and calcium carbonate. This conversion process for gypsum is not new. It was carried out for the first time on an industrial scale in Merseburg (Germany) in 1909 . Therefore, it is often called the Merseburg process.
More DetailsBewsey said his technology is relatively simple chemistry. In conventional ion exchange technology, sulfuric acid and lime are used, which results in the production of gypsum as a waste product. Conventional ion exchange does not effectively remove sodium chloride from the water, which means that treated water has to be diluted with clean water ...
More DetailsA continuous countercurrent flow process for converting FGD gypsum to ammonium sulfate and calcium carbonate including countercurrent flows with internal recycle of liquids to maximize the purity of reaction products while minimizing reaction times, and further include embodiments of the process that provide a yield of both ammonium sulfate and calcium carbonate to be 97 to , and ...
More DetailsAllen V. Barker, in Encyclopedia of Analytical Science (Third Edition), 2019 Sulfur-Containing Fertilizers (Organic and Conventional) Ammonium sulfate. Ammonium sulfate is a water-soluble granular fertilizer used to supply nitrogen when some acidification of soil is desirable. It is a sulfur-containing material with about 24% S. Ammonium sulfate is discussed also under nitrogen fertilizers.
More DetailsThe gypsum is used in the a rotary kiln calciner uses about 300 kg of wood per ton [1].The manufacture of hydraulic cements, ammonium sulfate fertilizer, monthly average energy consumption is of the order of 15000 sulphuric acid, and reclamation of acidic soil for agricultural kWh per ton.
More DetailsMagnesium based phosphate cement binder for composite panels: A response surface methodology for optimisation of processing variables in boards produced from …
More DetailsAmmonium sulfate has a high sulfur content in the sulfate form, making it readily absorbable by plants. It has a low pH, making it suitable for alkaline soils. As a nitrogenous fertilizer, it competes with urea, ammonium phosphates, and ammonium nitrate. Sulfur has become increasingly recognized as an essential nutrient for plant growth since ...
More DetailsA continuous countercurrent flow process for converting FGD gypsum to ammonium sulfate and calcium carbonate including countercurrent flows with internal recycle of liquids to maximize the purity of reaction products while minimizing reaction times, and further include embodiments of the process that provide a yield of both ammonium sulfate and calcium carbonate to be 97 to , and ...
More Details· In the dihydrate process to produce phosphoric acid, phosphate ore [Ca 10 F 2 (PO 4) 6] is leached with sulfuric and weak phosphoric acids to produce phosphoric acid and gypsum as a by‐product.Crystallization of gypsum occurs as the leaching is taking place. The effect of organic and inorganic additives on the structure and spectrum of gypsum crystals under simulated conditions of …
More Details· The primary product of ammonium sulfite was obtained, and the primary product will be oxidized to ammonium sulfate. After a series of refining processes, high value-added ammonium sulfate product [15] was obtained. Compared with the calcium method currently used in large-scale thermal power industry, ammonium method has obvious advantages.
More Details· The reactivity of flue gas desulphurization gypsum with ammonium carbonate has been studied in the temperature range (20–50) °C. Mechanism of this reaction was suggested and the kinetics parameters characterizing the reaction were determined. A mathematical model suitable for the prediction of the conversion of gypsum was proposed. The reaction is of the second order.
More DetailsThe new process takes waste gypsum or chalk and purifies it so that it can be used as high-grade white filler in plasterboard and cement. Firstly, impure gypsum is placed into a solution of ammonium sulfate around 90–100°C, together they form a complex. This complex sinks into the solution, releasing any impurities in the gypsum.
More Details· @article{osti_430286, title = {Manufacture of ammonium sulfate fertilizer from gypsum-rich byproduct of flue gas desulfurization: A prefeasibility cost estimate}, author = {Chou, M I.M. and Rostam-Abadi, M and Lytle, J M}, abstractNote = {Costs for constructing and operating a conceptual plant based on a proposed process that converts flue gas desulfurization (FGD)-gypsum to ammonium sulfate ...
More DetailsFIELD: chemistry. SUBSTANCE: group of inventions refers to the area of chemical technology, namely to the methods of production of wastes of chemical-recovery industry, chemical industry and petrochemical industry lfuric waste is filtered from organic suspended matter in filter 11. Sulfuric waste is neutralized using gas ammonia to pH 5.3-5.5 in neutralizer 8.
More DetailsEffect of Nitrate Salts on Solubility Behavior of Calcium Sulfate Dihydrate (Gypsum) in the Aqueous Sodium Chloride System and Physicochemical Solution Properties at 308.15 K. Journal of Chemical & Engineering Data 2014, 59 (3), 832-838.
More Details· Advanced Ammonium Sulfate Wet FGD Amy P Evans July 26, 2012
More DetailsModern Gypsum Production Process. Proceedings of the 14th international conference on environmental science and technology rhodes, greece, 3-5 september 2015 cest201501372 gypsum to gypsum from production to recycling papailiopoulou n.1, grigoropoulou h.1 and founti m.2 1 school of chemical engineering ntua, 2 school of mechanical engineering ntua, 9 heroon.
More DetailsManufacture of ammonium sulfate fertilizer from FGD-gypsum Millions of tone of FGD-gypsum by-product may be produced in this decade as a result of the 1990 Clean Air Act Amendments. In this research bench-scale experiments were conducted to obtain process data for the production of ammonium sulfate from FGD-gypsum and to help evaluate .
More DetailsNitrex has been reformulated with our new Ammonium Sulfate Nitrate Technology, giving you an ideal source of N for all seasons. Contains 5.0% (non-staining) Iron for that deep green color. This formulation will exceed all your expectations! * Available through select distributors.
More Details· Among the results, the purity of ammonium sulfate was all above 99% and the content of nitrogen was above 21%, which accorded with the national standard of excellent products. By comparing the spectra of ammonium sulfate in Fig. 8, It can be observed that the peak of the spectrum is mainly ammonium sulfate, and there is a non-obvious impurity ...
More Detailsammonium sulfate solution gypsum ammonium Prior art date 2012-08-10 Application number KR20157006216A Other languages Korean (ko) Other versions KR101588320B1 (en Inventor 머래이 피. 하시노프 테일러 퍼셀 요셉 에이. 살라 아서 알. 셜리 케이트 …
More DetailsAmmonium Sulfate / Ammonia-based FGD. Proprietary to and Patented by Marsulex Environmental Technologies. In the Ammonium Sulfate (AS) process, the absorption of SO 2 is accomplished with either anhydrous or aqueous ammonia and converts the captured SO 2 into a high value crop fertilizer. This advanced technology provides a unique solution ...
More DetailsJust before 10 AM on Mar. 6, 2012, the gypsum/ammonium sulfate/ammonium carbonate slurry was pumped to the converter from the pump tank. The goal of the run was to operate under the same conditions as the previous run in September 2011 with the FGD gypsum B to determine if the FGD gypsum A would react the same.
More Detailsammonium sulfate production from gypsum. Sales Inquiry Ammonium Sulfate Production From Gypsum; USGS Fact Sheet: Coal Combustion Products Sulfate is the preferred form of sulfur readily assimilated by crops, and ammonium sulfate is the ideal sulfate compound for soil supplements because it also provides nitrogen from the ammonium.
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